Melamine trisulfonic acid: An efficient and recyclable solid acid catalyst for the green synthesis of Biscoumarin derivatives

Iravani, Nasir; Keshavarz, Mosadegh; Mousavi, Maryam; Baghernejad, Mojtaba

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	Melamine trisulfonic acid: An efficient and recyclable solid acid catalyst for the green synthesis of Biscoumarin derivatives
Article 9, Volume 5, Issue 1, Winter 2015, Page 65-71 PDF (1.01 MB)
Document Type: Articles
Authors
Nasir Iravani ¹; Mosadegh Keshavarz²; Maryam Mousavi³; Mojtaba Baghernejad⁴
¹Department of Chemistry, Faculty of Science, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran.
²Department of Gas and Petroleum, Yasouj University, Yasouj, Zip Code 75918-74831, Iran
³Department of Chemistry, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran
⁴Young and Reasearcers Elite, Gachsaran Branch, Islamic Azad University, Gachsaran, Iran
Abstract
A novel catalytic synthesis of 3,3'-(arylmethylene)-bis-(4-hydroxy-2H-chromene-2-one) derivatives from a tandem condensation reaction of 4-hydroxycoumarin and aromatic aldehydes has been developed. The reaction occurs in water in the presence of Melamine trisulfonic acid as catalyst to give the corresponding products in good to high yields. This green approach has several advantages such as short reaction times, clean reaction profiles, and simple experimental and workup procedures. Moreover, the catalyst can be easily recovered by filtration and used at least seven times with only slight reduction in its catalytic activity. The results of the presented protocol in comparison with the different available catalysts in condensation reaction of benzaldehyde with 4-Hydroxycoumarin show that MTSA presented better results due to the structure of MTSA.
Keywords
Aromatic aldehydes; Biscoumarins; 4-hydroxycoumarin; Melamine trisulfonic acid


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