Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone

Document Type : Articles

Authors

1 Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran.

2 Nanotechnology Research Center, Research Institute of Petroleum Industry (RIPI), PO Box 1485733111, Tehran, Iran.

Abstract

A novel nanomagnetic material with a dimethylamino tag namely nano-Fe3O4@SiO2@R-NMe2 ([NFSRN]) was produced, and characterized by EDS, FT-IR, VSM, FE-SEM, XRD and TGA analyses. Then, it was applied as a highly effective and magnetically recyclable catalyst for the one-pot multi-component reaction of malononitrile, arylaldehydes and dimedone. Interestingly, in most entries, among the possible products which can be produced from the reactants, only 2-amino-tetrahydrobenzo[b]pyrans were obtained in high yields and relatively short times, and no other product was obtained.  

Graphical Abstract

Novel nanomagnetic material with dimethylamino tag: a selective and recyclable catalyst for the reaction of malononitrile, aryl aldehydes and dimedone

Highlights

  • Preparation of a nanomagnetic material with a dimethylamino tag.
  • Full Characterization of the nanomaterial.
  • Application of the nanomaterial as a selective catalyst for an organic reaction.
  • Formation of 2-amino-tetrahydrobenzo[b]pyrans among the possible products.

Keywords


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