Fe3O4@SiO2@Vitamin C@Fe2O3 Nanoparticles as a Novel Green Catalyst for One-pot Synthesis of 3-amino-1-aryl-1H-benzo[f]chromene-2-carbonitrile Derivatives

Document Type : Articles

Authors

Department of Chemistry, Faculty of Science, University of Guilan, Rasht P.O. Box 41335-1914, Iran

Abstract

In this research, we report a novel and green magnetic nanocatalyst; Fe3O4@SiO2@Vitamin C@Fe2O3 for clean synthesis of 3-amino-1-aryl-1H-benzo[f]chromene-2-carbonitriles with high-yield in water as solvent at room temperature. The nanocatalyst is stable under the synthetic conditions and it can be reused several times without considerable reduction in its catalytic activity. The catalyst structure was characterized by using various analytical techniques; SEM, FT-IR, thermogravimetric analysis (TGA), UV-vis spectroscopy, VSM and EDS. Also, the products were separated and characterized by determining their melting points, IR spectra and compared to those of the authentic samples.  Environmentally friendly, availability, high catalytic activity and ease of separation are the main reasons for using Fe3O4@SiO2@Vitamin C@Fe2O3 as a green catalyst.

Graphical Abstract

Fe3O4@SiO2@Vitamin C@Fe2O3 Nanoparticles as a Novel Green Catalyst for One-pot Synthesis of 3-amino-1-aryl-1H-benzo[f]chromene-2-carbonitrile Derivatives

Highlights

  • This research describes the catalytic activity of a nano-composite made of the materials which are readily available and quite prevalent in nature.
  • The nanoparticles efficiently catalyze the synthesis of 3-amino-1-aryl-1H-benzo[f]chromene-2-carbonitriles derivatives and this method is superior in terms of the reaction temperature, using green solvent and yields.
  • No side reactions, product’s purity and yield enhanced by Fe3O4@SiO2@Vitamin C@ Fe2O3 as a green magnetic catalyst.
  • Clean separation and recyclability of the catalyst

Keywords


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