Nano-[SiO2@R-Im-SO3H][CF3COO]: an effectual catalyst for the production of bis-coumarins and N,N′-alkylidene bisamides

Document Type : Articles

Authors

Department of Chemistry, Payame Noor University, PO Box 19395-3697, Tehran, Iran

Abstract

A novel organic-inorganic hybrid nanomaterial namely nano-[SiO2@R-Im-SO3H][CF3COO] (NSRISC) was synthesized, and characterized using FT-IR, EDS, FE-SEM, TGA and XRD analyses. Thereafter, the solvent-free production of bis-coumarins (from aryl aldehydes and 4-hydroxycoumarin) and N,N′-alkylidene bisamides (from aryl aldehydes and benzamide) was catalyzed by NSRISC. Bis-coumarins were produced in 86-97% at 100 ºC, and bisamides were obtained in 87-97% at 105 ºC. The reaction times were 15-30 min for both kinds of compounds.

Graphical Abstract

Nano-[SiO2@R-Im-SO3H][CF3COO]: an effectual catalyst for the production of bis-coumarins and N,N′-alkylidene bisamides

Highlights

 (1) Preparation of a novel organic-inorganic hybrid nanomaterial.

(2) Full characterization of the nanomaterial.

(3) Catalytic performance of the nanomaterial for the production of bis-coumarins and N,N′-alkylidene bisamides.

Keywords


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Volume 12, Issue 2
June 2022
Pages 127-137
  • Receive Date: 25 April 2021
  • Revise Date: 07 February 2022
  • Accept Date: 11 February 2022
  • First Publish Date: 13 March 2022